CeO2@TiO2 enrichment XRF method for rapid detection of multiple elements in drinking water
GUO Ya-qing, ZHOU Tao-hong, HU Jia-yong, HUANG Hui, JI Wei-hao, PENG Qing-zhi
2025, 64(1):
126-132.
doi:10.14088/j.cnki.issn0439-8114.2025.01.022
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CeO2 was synthesized using sodium hydroxide particles and cerium nitrate hexahydrate crystals, followed by reaction with tetrabutyl titanate and calcination for the preparation of CeO2@TiO2 compound material. Enrichment, elution and XRF rapid detection of Pb, As, Cd, Cr, Fe, Cu, Zn, and Sr elements in drinking water were performed. The results indicated that CeO2@TiO2 compound material could simultaneously enrich Pb, As, Cd, Cr, Fe, Cu, Zn and Sr elements in drinking water, with an optimal adsorption pH of 6~8 and an optimal adsorption time of 5 minutes;using 2% nitric acid or 1% sodium hydroxide as eluent, the elution rates of each element reached their maximum values after 10 minutes of elution;under optimal adsorption conditions,when the addition amount of each element was 20 μg, the adsorption rate of the CeO2@TiO2 composite material for each element was relatively high, all exceeding 90%. CeO2@TiO2 compound material had certain renewable properties and could be recycled at least 6 times;when the enrichment factor was 10 times, the detection limits of Pb, As, Cd, Cr, Fe, Cu, Zn and Sr elements were 6.0, 5.6, 2.7, 30.9, 15.4, 14.7, 15.2, and 4.8 μg/L, respectively. The relative standard deviations (RSD) of Pb, As, Cd, Cr, Fe, Cu, Zn, and Sr elements were 2.02%~5.46%. This method could be used for rapid on-site detection of Pb, As, Cd, Cr, Fe, Cu, Zn and Sr elements in drinking water.