Rapid determination of ten inorganic elements in animal muscle by graphite digestion-inductively coupled plasma mass spectrometry
WANG Xiao, CHANG Chen-yang, SHAO Li, LUN Cai-zhi
2022, 61(23):
155-159.
doi:10.14088/j.cnki.issn0439-8114.2022.23.031
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A method was established for the determination of ten elements in animal muscle by graphite digestion-inductively coupled plasma mass spectrometry and the contents of each element were analyzed. With chicken as raw material, the type, dosage, digestion time, temperature and other parameters of the digestion reagent were optimized to determine the optimal graphite digestion conditions, and the matrix interference was eliminated by the on-line internal standard addition method. The results showed that chromium, manganese, cobalt, nickel, copper, arsenic, cadmium and lead had a good linear relationship at the mass concentration of 0~500 ng/mL, and iron and zinc had a good linear relationship at the mass concentration of 0~1 000 ng/mL (r≥ 0.999 9). The recovery rate of each element was 88.5%~99.3%, and the RSD was 0.15%~1.64%(n=6). In the actual sample determination, the contents of chromium, arsenic, cadmium and lead in five kinds of animal muscles were lower than the limit requirements of the current national standards, and the contents of manganese, iron, copper, zinc 4 kinds of human body essential elements were abundant. The graphite digestion-inductively coupled plasma mass spectrometry method was suitable for the simple, rapid and accurate determination of 10 elements of chromium, manganese, iron, cobalt, nickel, copper, zinc, arsenic, cadmium and lead in animal muscle.