湖北农业科学 ›› 2020, Vol. 59 ›› Issue (12): 72-74.doi: 10.14088/j.cnki.issn0439-8114.2020.12.015

• 资源·环境 • 上一篇    下一篇

预处理与双膜法组合工艺处理农药厂含磷生化尾水研究

白祖国, 彭文博, 谢静, 丁邦超, 杨积衡   

  1. 江苏久吾高科技股份有限公司,南京 211808
  • 收稿日期:2019-08-01 发布日期:2020-08-26
  • 作者简介:白祖国(1988-),男,湖北荆州人,中级工程师,硕士,主要从事膜集成技术在化工及水处理中的应用研究,(电话)15195908043(电子信箱)509914042@qq.com。
  • 基金资助:
    国家“863”计划课题(2012AA03A606)

Study on the combined pretreatment and double membrane process for the treatment of phosphorous tail water in pesticide plant

BAI Zu-guo, PENG Wen-bo, XIE Jing, DING Bang-chao, YANG Ji-heng   

  1. Jiangsu Jiuwu Hi-Tech Co. Ltd., Nanjing 211808, China
  • Received:2019-08-01 Published:2020-08-26

摘要: 采用“预处理+超滤+纳滤”工艺对浙江某农药厂生化尾水进行深度处理试验,通过改变投药量、超滤和纳滤操作压力和回收率,探讨了预处理和双膜法深度处理农药厂生化尾水的最佳工艺条件。结果表明,聚合硫酸铁投加量在300 mg/L的条件下,预处理出水效果达到超滤进水要求。超滤操作压力控制在0.1~0.2 MPa,回收率90%;纳滤操作压力控制在2.0~2.2 MPa,回收率80%,膜处理性能较好。废水经双膜法处理后,总磷降至8 mg/L以下,COD去除率90%以上,出水浊度小于0.1 NTU,完全达到含磷废水排放标准。

关键词: 预处理, 双膜法, 深度处理, 含磷废水

Abstract: The study on the secondary biochemical effluent of agricultural pharmaceutical factory by using pretreatment, ultrafiltration and nano-filtration technology are carried out. By changing the dosage, pressure and recovery rate, the optimum process conditions of the secondary biochemical effluent of agricultural pharmaceutical factory discussed by using pretreatment and double-membrane process technology. The results show that the pretreatment effluent effect meet ultrafiltration water requirements under the condition of PFS dosage 300 mg/L. The membrane system runs stably when the ultrafiltration operating pressure control in 0.1~0.2 MPa, recovery rate 90% and nano-filtration operating pressure control in 2.0~2.2 MPa, recovery rate 80%. After the double-membrane treatment, wastewater TP decreases to 8 mg/L, the removal rate of COD is above 90%, the effluent turbidity is less than 0.1 NTU. Effluent quality reaches the level of new emission standards.

Key words: pretreatment, double-membrane method, depth processing, phosphorus-containing wastewater

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