湖北农业科学 ›› 2020, Vol. 59 ›› Issue (8): 66-70.doi: 10.14088/j.cnki.issn0439-8114.2020.08.014

• 资源·环境 • 上一篇    下一篇

响应曲面法优化富马酸废水预处理工艺条件

黄彪1, 范聪颖2, 兰天翔2   

  1. 1.湖北华信中正检测技术有限公司,武汉 430000;
    2.长江大学化学与环境工程学院,湖北 荆州 434023
  • 收稿日期:2019-05-12 出版日期:2020-04-25 发布日期:2020-07-03
  • 作者简介:黄 彪(1986-),男,湖北汉川人,工程师,硕士,主要从事环境监测及治理方面的研究工作,(电话)18802728677(电子信箱)453881520@qq.com。

Optimization of pretreatment process conditions for fumaric acid wastewater by response surface methodology

HUANG Biao1, FAN Cong-ying2, LAN Tian-xiang2   

  1. 1. Hubei Huaxin Zhongzheng Testing Technology Co.,Ltd.,Wuhan 430000,China;
    2. College of Chemistry and Environmental Engineering,Yangtze University,Jingzhou 434023,Hubei,China
  • Received:2019-05-12 Online:2020-04-25 Published:2020-07-03

摘要: 采用三维电化学法预处理富马酸废水,重点考察废水的NH4+-N去除率。基于BBD响应曲面法,探究了电压、反应时间和初始pH的单独及相互作用,并建立氨氮去除率的数学模型。结果表明,影响因子显著性顺序为电压>反应时间>初始pH,三者之间有一定的交互作用,但并不显著;数学模型回归性较好,预测氨氮最大去除率为88.7%,最佳运行条件组合为电压28.41 V、反应时间87.27 min、pH 4.55,验证试验结果为87.6%,与预测值的偏差仅为1.2%。

关键词: 响应曲面优化法, 三维电化学, 富马酸废水, 氨氮去除率

Abstract: The three-dimensional electrochemical method was used to pretreat fumaric acid wastewater, and the removal rate of ammonia nitrogen was mainly studied. Based on the BBD response surface method, the individual and interaction of voltage, reaction time and initial pH were explored, and a mathematical model of ammonia nitrogen removal rate was established. The results show that the significant order of influence factors is voltage>reaction time>initial pH, and there is a certain interaction among the three, but it is not significant. A satisfactory prediction quadratic polynomial equation was derived by response surface methodology. The maximum removal rate of ammonia nitrogen is predicted to be 88.7%. The optimum operating conditions are: The voltage is 28.41 V, the reaction time is 87.27 min, and the pH is 4.55. Using the above best conditions, the ammonia nitrogen removal rate of 87.6% was obtained, which is consistent with the predicted value of 1.2%.

Key words: response surface optimization method, three-dimensional electrochemistry, fumaric acid wastewater, ammonia nitrogen removal rate

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