低分子有机酸对石灰性土壤中Pb、Cd的淋洗效应

doi:10.14088/j.cnki.issn0439-8114.2018.06.010

湖北农业科学 ›› 2018, Vol. 57 ›› Issue (6): 43-46.doi: 10.14088/j.cnki.issn0439-8114.2018.06.010

低分子有机酸对石灰性土壤中Pb、Cd的淋洗效应

刘桂华¹, 任婧¹, 胡岗¹, 秦松^{1, 2, 3}, 范成五^{1, 2}

1.贵州省农业科学院土壤肥料（农业资源与环境）研究所,贵阳 550006;
2.贵州省农业资源与环境工程技术研究中心,贵阳 550006;
3.农业部贵州耕地保育与农业环境科学观测实验站,贵阳 550006

收稿日期:2017-10-30 出版日期:2018-03-25 发布日期:2020-01-06
通讯作者: 范成五,副研究员,主要从事农业资源利用与环境研究,（电子信箱）gzfcw@163.com
作者简介:刘桂华（1989-）,女,贵州铜仁人,助理研究员,硕士,主要从事农业环境重金属污染治理研究,（电话）15185071003（电子信箱）740768802@qq.com。
基金资助:
贵州省科学技术基金项目（黔科合J字[2013]2174号）; 贵州省农业科学院青年基金[2017]13号; 贵州省科研机构服务企业行动计划项目（黔科合服企[2015]4007）

Effects of Low Molecular Organic Acids on the Removing of Pb,Cd in Calcareous Soils

LIU Gui-hua¹, REN Jing¹, HU Gang¹, QIN Song^1,2,3, FAN Cheng-wu^1,2

1.Institute of Soil and Fertilizer（Resources and Environment for Agriculture）, Guizhou Academy of Agricultural Sciences,Guiyang 550006,China;
2.Guizhou Research Center for Agricultural Resources and Environmental Engineering Technology,Guiyang 550006,China;
3.Field Monitoring Experimental Station for Cultivated Land Preservation and Agro-environment in Guizhou, Ministry of Agriculture of China,Guiyang 550006,China

Received:2017-10-30 Online:2018-03-25 Published:2020-01-06

摘要/Abstract

摘要： 采用振荡淋洗方法研究柠檬酸、苹果酸、酒石酸3种常见低分子有机酸对污染石灰土壤中Pb、Cd的淋洗净化效应。结果表明,与对照（CK）相比,随着3种有机酸添加浓度的增加,均可显著增加土壤中Cd的解吸量（P<0.05）;而苹果酸、酒石酸在各添加浓度下均能不同程度抑制土壤中Pb的解吸,柠檬酸在较低添加浓度下抑制,而在较高浓度下（>10.0 mmol/L）又能促进Pb的解吸。Pb、Cd的解吸率曲线表明,同一有机酸对土壤中不同重金属（Cd、Pb）的解吸规律（促进解吸、抑制解吸）存在明显差异,不同有机酸对土壤中同一重金属（Cd或Pb）的解吸量也存在明显差异。Pb的解吸分配系数（K_d）呈钟形分布,而Cd的K_d则随有机酸浓度的增加呈减小趋势。

关键词: 低分子有机酸, 解吸, 石灰性土壤, 镉, 铅

Abstract: The effects of citric acid, malic acid and tartaric acid on leaching of Pb,Cd in contaminated soil were researched by oscillating methods. The results showed that compared with the control,desorption amount of Cd significantly increased with the addition of citric acid,malic acid and tartaric acid（P<0.05）. Malic acid and tartaric acid inhibited the desorption of Pb in different degree. Citric acid in low concentration inhibited but promoted in high concentration（>10.0 mmol/L） the desorption of Pb. The desorption rate curve indicated that the effect of the same or different organic acid on different heavy metal or the same heavy metal（promotion and inhibition） varied obviously. The desorption distribution coefficient of Pb（K_d） presented bell-shaped distribution,but the K_d of Cd decreased with organic acid increasing.

Key words: low molecular organic acids, leaching desorption, calcareous soil, Cd, Pb

中图分类号:

刘桂华, 任婧, 胡岗, 秦松, 范成五. 低分子有机酸对石灰性土壤中Pb、Cd的淋洗效应[J]. 湖北农业科学, 2018, 57(6): 43-46.

LIU Gui-hua, REN Jing, HU Gang, QIN Song, FAN Cheng-wu. Effects of Low Molecular Organic Acids on the Removing of Pb,Cd in Calcareous Soils[J]. HUBEI AGRICULTURAL SCIENCES, 2018, 57(6): 43-46.

参考文献

[1] LI Y J,HU P J,ZHAO J,et al.Remediation of cadmium-and lead-contaminated agricultural soil by composite washing with chlorides and citric acid[J].Environmental Science and Pollution Research,2015,22(7):5563-5571.
[2] 熊严军. 我国土壤污染现状及治理措施[J].现代农业科技,2010(8):294-295.
[3] 崔力拓,耿世刚,李志伟.我国农田土壤镉污染现状及防治对策[J].现代农业科技,2006(11):184-185.
[4] 赵志鹏,邢丹,刘鸿雁,等.典型黄壤和石灰土对Cd的吸附解吸特性[J].贵州农业科学,2015,43(6):83-86.
[5] MAKINO T,SUGAHARA K,SAKURAI Y,et al.Remediation of cadmium contamination in paddy soils by washing with chemicals:Selection of washing chemicals[J].Environmental Pollution,2006,144(1):2-10.
[6] 吴烈善,咸思雨,孔德超,等.单宁酸与柠檬酸复合淋洗去除土壤中重金属Cd的研究[J].环境工程,2016,34(8):178-181.
[7] TAMM O.Eine methode zur bestimmung der anorganischen komponenten des gelkomplexes im boden[J].Medd Statens Skogsforsoksanst,1922,19:387-404.
[8] DERMONT G,BERGERON M,MERCIER G,et al.Soil washing for metal removal:A review of physical/chemical technologies and field applications[J].Journal of Hazardous Materials,2008, 152(1):1-31.
[9] 周代兴,李汕生.防治铊污染土壤的初步试验[J].土壤学报,1982, 19(4):409-411.
[10] 李海波,李培军,孙铁珩,等.用淋洗法修复张士灌区Cd,Pb污染沉积物的研究[J].农业环境科学学报,2005,24(2):328-332.
[11] 赵娜,崔岩山,付彧,等.乙二胺四乙酸(EDTA)和乙二胺二琥珀酸(EDDS)对污染土壤中Cd、Pb的浸提效果及其风险评估[J].环境化学,2011,30(5):958-963.
[12] 刘霞,王建涛,张萌,等.螯合剂和生物表面活性剂对Cu、 Pb污染塿土的淋洗修复[J].环境科学,2013,34(4):1590-1597.
[13] FISCHER K,BIPP H P.Removal of heavy metals from soil components and soils by natural chelating agents. Part П. Soil extraction by sugar acids[J].Water,Air and Soil Pollution,2002, 138(1):271-288.
[14] 钱翌,刘莹.单一及复合有机酸对土壤中镉形态的影响研究[J].土壤通报,2012,43(1):186-189.
[15] 王淑君,胡红青,李珍,等.有机酸对污染土壤中铜和镉的浸提效果[J].农业环境科学学报,2008,27(4):1627-1632.
[16] 许超,夏北城,林颖.柠檬酸对中低污染土壤中重金属的淋洗动力学[J].生态环境学报,2009,18(2):507-510.
[17] WU L H,LUO Y M,CHRISTIE P,et al.Effects of EDTA and low molecular weight organic acids on soil solution properties of a heavy metal polluted soil[J].Chemosphere,2003,50(6):819-822.
[18] 许端平,李晓波,孙璐.有机酸对土壤中Pb和Cd淋洗动力学特征及去除机理[J].安全与环境学报,2015,15(3):261-266.
[19] NAJAFI S,JALALI M.Effects of organic acids on cadmium and copper sorption and desorption by two calcareous soils[J].Environmental Monitoring and Assessment,2015,187(9):585.
[20] GAO Y Z,HE J Z,LING W T,et al.Effects of organic acids on copper and cadmium desorption from contaminated soils[J].Environment International,2003,29(5):613-618.
[21] XIONG X,STAGNITTI F,TUROCZY N,et al.Competitive sorption of metals in water repellent soils: Implications for irrigation recycled water[J].Australian Journal of Soil Research,2005,43(3):351-356.
[22] REED B E,CARRIERE P C,MOORE R.Flushing of a Pb(Ⅱ) contaminated soil using HCl,EDTA,and CaCl₂[J].J Environ Eng,1996,122(1):48-50.
[23] 李小平,徐长林,张旭,等.城市土壤重金属有机酸淋溶特征与动力学机制[J].水土保持通报,2014,34(6):6-12.
[24] YU J Z,KLARUP D.Extraction kinetics of copper, zinc, iron and manganese from contaminated sediment using disodium ethylenediaminetetraacetate[J].Water, Air and Soil Pollution,1994,75(2):205-225.
[25] ABUMAIZAR R,KHAN L I.Laboratory investigation of heavy metal removal by soil washing[J].Journal of the Air and Waste Management Association,1996,46(8):765-768.
[26] 可欣,李培军,张昀,等.利用乙二胺四乙酸淋洗修复重金属污染的土壤及其动力学[J].应用生态学报,2007,18(3):601-606.
[27] YOBOUET Y A,ADOUBY K,TROKOUREY A,et al.Cadmium,copper,lead and zinc speciation in contaminated soils[J].International Journal of Engineering Science and Technology,2010,1(2):802-812.
[28] 吴燕玉,王新,梁仁禄,等.Cd、Pb、Cu、Zn、As复合污染在农田生态系统的迁移动态研究[J].环境科学学报,1998,18(4):407-412.
[29] RUAN X L,ZHANG G L,NI L J,et al.Distribution and migration of heavy metals in undisturbed forest soils:A high resolution sampling method[J].Pedosphere,2008,18(3):386-393.
[30] 徐明岗,李菊梅,张青.pH对黄棕壤重金属解吸特征的影响[J].生态环境,2004,13(3):312-315.
[31] BEGUM Z A,RAHMAN I M M,TATE Y,et al. Remediation of toxic metal contaminated soil by washing with biodegradable aminopolycarboxylate chelants[J].Chemosphere,2012,87(10):1161-1170.

低分子有机酸对石灰性土壤中Pb、Cd的淋洗效应

Effects of Low Molecular Organic Acids on the Removing of Pb,Cd in Calcareous Soils

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